what's the archaeological evidence for malt?

This is something that I became more and more interested in, once I had completed and submitted my thesis. How does an archaeologist or an archaeobotanist recognise whether or not a grain is malted? What happens inside the grain on the malting floor? I had access to the University Library for a few years after my degree - by teaching archaeology classes in the Continuing Education Department. I explored sections of the Library that, perhaps, no archaeologist had visited before. I studied grain germination physiology, biochemistry and discovered that Bewley and Black's classic study of seed germination was the best.

Malting is an important craft and technology. The main reason for making malt is to brew with it, or more specifically, to make an ale or beer from the wort. Malt is also the main ingredient for whiskey, of course, but I am most interested in malt and ale in prehistory and its' role in the origin of grain agriculture. Apart from grain barns and malting floors, it seems that the best archaeological evidence for malt lies within the grain itself. There are clear physiological indications, depending upon whether the grain is desiccated (dried) or carbonised (charred).

Carbonised or charred grains are frequently found in archaeological excavations from the neolithic, when people first began to cultivate and process grain, right through to the medieval era and beyond. Carbonised grains are found all over northern Europe.

What do they signify?

Is it evidence of a grain store or granary that has been destroyed by fire? This was suggested in interpretations of excavations of an huge rectangular timber building at Balbridie, Fife, Scotland where thousands of carbonised grains were found?

Perhaps the grain dryer in a barn caught fire, while they were drying the harvested grain or oats. Or was it a kilning of the malt, which has gone disastrously wrong?

Lots of grain barns have burned down over the years, as well as traditional malthouses. It's not an unusual event. Even in recent times, as late as the 1960s, malthouses have been known to catch fire.

Carbonised grains were found at Eberdingen-Hochdorf, where there were the remains of Iron Age malting and brewing. This Iron Age site was excavated by Professor Hans Peter Stika between 1989 and 1993. According to the excavation report, it was a high status site, probably the rural residence of a prince. The carbonised grains, a huge number of them, were found in a sort of U shaped ditch, together with bits of charred wood. The interpretation was that as the malt was being dried, the fire had got out of control and set fire to both the wooden platform upon which the malt had been laid, as well as carbonising all the malt. The charred grains were mostly barley. Many of them had missing embryos and the grain was in poor condition.

They were identified as having been deliberately malted using these criteria:
... groove like channels on the dorsal sides
... the dorsal side becomes concave
... the coleoptile and coleorhizae become more prominent
... germination roots develop
... separated or fragmented embryos
... germination was even, meaning that it was deliberate and intentional

A recent excavation at another Iron Age site has also identified the activities of making malt and brewing by examining the charred grain. Another accidental fire had preserved the malt as it was being dried in the 5th Century BC at Roquepertuse in south eastern France. The sample of grain was taken from the floor of a building, close to a hearth and an oven. The excavators describe it like this:

"In spite of favourable conditions for the preservation of seeds in the sediment, which was rich in ash, charcoal and generally carbonised plant material, the grains are corroded and highly fragmented. This fairly poor preservation seems rather specific to the barley grains from this sample. Conditions are therefore not suitable for a satisfactory observation of all the morphological features of most of the grains. However, the best preserved specimens allow the assessment that slightly more than 90% of the grains were sprouted when carbonised. This is easily visible from the groove like channel on the dorsal side of the grains. As far as we can see, the sprout length is not perfectly uniform, but it generally reaches about two thirds the length of the grain. 

The poor preservation of barley grains is probably caused by germination, which tended to render them brittle. Fragmentation occurred mostly after carbonisation and is therefore not due to Iron Age human practices." Bouby et al, 2011, Never mind the bottle. Archaeobotanical evidence for beer brewing in Mediterranean France and the consumption of alcoholic beverages during the 5th Century BC

It's beginning to get a little bit technical here and, perhaps, a good time to explain some of the grain germination jargon. There is a lot of it, so I shall stick to the basics. The fundamental biochemical processes and the physiological changes of grain germination occurred in ancient grains just as they do today, in modern grains. It doesn't matter whether you make malt 10,000 years ago or 5000 years ago or 10 minutes ago, the biochemistry of grain germination remains the same.

Grains are a lot plumper than they used to be, because of selection and development by farmers over the millennia. The aleurone layer, a special layer of cells just beneath the husk, is three or four cells in depth in modern grains, rather than the one or two cells in ancient grains. The structure of ancient cereal grains was studied by Professor Geoffrey Palmer, who looked at 3000 year old grain from Amarna, Egypt. Using a scanning electron microscope to investigate ancient desiccated grains, he found that the internal structure remained intact. Individual starch granules within the endosperm could be seen with little holes or pits, where the enzymes had begun to convert grain starch into sugars. There are lots of wonderful scanning electron microscope images in his paper.

Carbonised, or charred grain is found on many archaeological sites in Northern Europe and the British Isles. The matrix of charred or carbonised grain has been destroyed by heat of the fire, so it is not possible to look at individual starch granules. Although carbonised grain is often used just to provide a radiocarbon date for the site, there might be other clues for the archaeologist and archaeobotanist that reveal what kind of grain processing techniques were taking place. Such as separated embryos, fragmentation and friability.

what happens on the malting floor?
Barley, wheat, oats, sorghum and rye can all be malted. I hope these diagrams of grain and malt will help to explain how the grain germinates. This is how it works at a basic level.

When the grain has been sufficiently steeped and aerated in water, growth hormones (gibberellin) are activated in the scutellum and embryo. These growth hormones stimulate the production of enzymes in the aleurone layer, which is a thin layer of special cells, just beneath the husk.


The maltster knows, through skill and experience, when the grain is sufficiently steeped. The wet grain is transferred to the malting floor, where it is piled up, then gradually raked out into a bed, a few inches deep. Here it begins to germinate. When rootlet and shoot are about one third the length of the grain, it is called green malt, and the next stage is to carefully dry it. 

Biochemical changes occur within the grain as it germinates on the floor. The enzymes that were activated within the aleurone layer begin to convert grain starch into sugars, the initial food source for the growing grain. These are the same enzymes that re activate in the mash tun and make a sweet mash. Other enzymes break down the husk, making the grain friable and, therefore, easier to crush than unmalted grain.

Malt, therefore, is made up of mostly starch, with a few sugars and, most importantly, those dormant starch converting enzymes that re activate in the mash tun at the right temperature.

Grain germination has a complex biochemistry. Scientists still don't fully understand how the aleurone layer works. If you want to know more detail, have a look here. If you want to read even more detail, have a look here, at chapter 14 of 'Barley: production, improvement and uses' by Steven Ullrich. Or get hold of a copy of Bewley and Black.

The products of brewing are ephemeral. Malt goes into the mash tun. Wort is fermented into ale which people drink and spent grain is fed to animals and waste liquid is washed down the drains. For the maltster and the brewer, it is a tragedy if the grain barn is destroyed by fire while the malt is being dried. For the archaeologist and archaeobotanist, it is a wonderful thing because the grain is carbonised and it is therefore preserved for analysis.

drying the green malt
Straight off the malting floor, it is called green malt. The maltster stops the growing process by gently drying the malt in a kiln. Gentle heat does not destroy the enzymes. Warm air passes through the malt, usually over several days. Traditional grain drying kilns do not have a solid floor. The malt is put upon a permeable floor to dry, so that warm air passes through the grain bed. Making good malt is a skilful task.

Today, maltsters produce a variety of types of malt by kilning at different temperatures. Base malts are kilned at lower temperatures. The enzymes are not destroyed and will remain active in the mash tun. Specialty malts are kilned at higher temperatures, destroying the enzymes. These provide only colour and flavour to the beer, making up no more than 10% of the grain bill in the mash tun. Specialty malts have been developed over the last two hundred years, making a wide range of beers possible from pale ale to dark stout.

SEMs of carbonised grain from Balbridie 'timber hall', Fife, Scotland
I spent a few years making funding applications, hoping to continue my research into the archaeological evidence for malt. That never happened but, working with the Satake Centre for Grain Process Engineering at UMIST, Manchester, I was able to get some scanning electron images of ancient carbonised grain from a neolithic site in Scotland.

The SEM images below were taken to accompany our funding applications and they were not originally intended for publication, but I think enough time has passed for me to now put them up on my blog and share them. The SEM work was done by a brewing research student. I am sorry to say I don't know her name and I did not get to meet her.

I was given six tiny carbonised grains from the thousands that had littered the floor of a 6000 year old, early neolithic rectangular timber building in Scotland. The building was destroyed by fire. Professor Ian Ralston, one of the original excavators, was kind enough to send me them. Three of the grains had missing embryos, visible with the naked aye and very clear under a normal microscope. One of the grains was examined using a scanning electron microscope and it shows the missing embryo, on the right, indicating that it has begun to germinate.

More of the grains from the site would need to be examined, to identify how many had begun to germinate. If it turns out to be a high percentage, and if the grains are friable and poorly preserved, then this is a deliberate malting for the production of ale in neolithic Scotland. Several SEM images of the same grain were made. The image below shows that the endosperm of the grain has been badly damaged by the fire. But it is possible to just about see the aleurone layer, beneath the husk.

Moving in closer to see the detail of the husk, we were very surprised indeed to see that the aleurone layer, that special layer of cells that kick starts the germination process, is visible, intact and well preserved. The husk has begun to be broken down by other enzymes, as can be seen in the bottom left of the image, and the grain was friable and fragile. All these are good indications of being malted.

This final image of that little carbonised grain show how well the individual cells of the aleurone layer have been preserved. They look rather like sponges, and some appear to have been activated. The more you look at this image, the more detail you can see. It is possible to make out erosion pits, beneath the individual aleurone layer cells, that indicate that the enzymes have begun to hydrolyse starch into sugars.

This is my favourite SEM image of an ancient grain. I think it would be a very good research project for someone to look at ancient carbonised grain from as many sites as possible. Changes in the aleurone layer cells and degradation of the husk might prove to be important criteria for the identification of malt. 

********************************************

trough mashing, tridents, fire cracked stones and ale

introduction and update
This blog discusses some of the practical and technical details of mashing in, Neolithic and Bronze Age style. It's about troughs and tridents, hot rocks and prehistoric burnt mounds. It was first published in the summer of 2014. I've edited it, added a few more details and brought it a bit more up to date. Why did I do this? Because it's now 17th February 2022 and the World of Stonehenge Exhibition has just opened at the British Museum in London. Among the 400 wonderful exhibits are two large wooden tridents, carved from solid oak and each measuring over two metres long. They were discovered near Stainton, Carslisle, in 2013. What were these mysterious objects used for? Archaeologists were puzzled. Suggestions at the time included eel spears or hay forks, neither being particularly convincing.

There was quite a lot of discussion on social media about the various possible and probable uses for these enigmatic objects made from solid oak. I'll try and find a link to it. It was a lively and, at times, argumentative discussion.

One suggestion that Graham and I made at the time was that these wooden tridents were ideal as mash forks, a traditional tool used for stirring the crushed malt into hot water in the 'mashing in' part of the ale and beer brewing process. Initially the idea was met with some negativity and suspicion. However, it now seems to be one of the accepted interpretations and, I am pleased to report, is included in the newly published book of the 'The World of Stonehenge' Exhibition:

"The tridents may have been used for fishing or eel trapping, or in agricultural activities as hay forks, and even as mashing forks in the process of beer brewing. It is likely that farmers were using some of their cereal harvests to make alcohol for social and religious gatherings rather than consuming only sober porridge and savoury foods." 

(Garrow, D. & Wilkin, N. The World of Stonehenge, published by The British Museum, 2022 page 50)

(© Tullie House Museum and Art Gallery Trust)
This image is from a news item in Archaeology, Friday December 6th 2013. see:https://www.archaeology.org/news/1610-england-neolithic-wooden-tridents

At the World Archaeology Conference (WAC 6) in Dublin, 2008, archaeologists from the Moore Group demonstrated how to mash in a wooden trough using fire heated stones. They used a garden fork to transfer the stones into the trough.  Inspired by their brewing experiments Graham and I mashed in a replica stone trough at Bressay, Shetland, the site of a Bronze Age burnt mound, in the summer of 2011. We used a garden fork to stir the mash and, at the time, we wished that the handle of the fork could have been longer. Something like these tridents would have been perfect for the job. See our blog trough, mash and wort for more details of these experiments and demonstrations.

These two wooden tridents were carved from single pieces of oak and would certainly have been sturdy enough for the task of stirring the mash in a trough in the ground. They would also have been suitable to remove hot stones from a fire, transferring them into the trough of water in order to heat it and maintain a good mash temperature. The tridents have been dated to c3650 BC and were found in a palaeochannel at Stainton, a site associated with burnt mounds and much more. See here for more details of the excavations. 

And now, after this updated introduction, let's go back to the blog that we wrote in the summer of 2014:

what is a burnt mound?  

In Ireland, over 5000 burnt mound sites are known. In Scotland, about 1900 have been excavated so far. They also found in England and Wales. The burnt mound itself is a pile of fire reddened and cracked stones, often in a semi-circular shape as they have been thrown onto the heap. The stones were put into a fire to be heated up, then dropped into a trough of water in order to heat it. There are many things that hot water can be used for.

Archaeologists agree that burnt mound sites are something to do with hot rock technology - using hot stones to heat lots of water - but to what purpose? That's what archaeologists can't agree on. There have been several suggestions:

- they were used to cook meat. The idea is that you wrap a big piece of meat in straw and leave it in the heated water trough for several hours. You probably have to keep putting more hot stones in, as the water cools. There are easier and more efficient ways of cooking meat.

- they were a sauna or sweat lodge. I don't understand this. In my experience, a sauna has a few hot stones upon which water is splashed to make steam. You don't need a large trough of water and lots of hot stones.

- you can wash sheep fleece or wool in them. This seems to be a practical idea. Fleece must be washed before it is spun into wool for clothing.

None of these suggestions are controversial. Most people reckon that the troughs would have been multi functional - a bit like the kitchen sink only much bigger. When it was suggested that these sites could have been used for making beer, some archaeologists became ever so slightly annoyed. Although the idea was first put forward in 2007, backed by successful experimental work and sound brewing theory, it is still considered by some to be controversial. I don't know why. 

Hot rocks are ideal for heating large amounts of water to the perfect temperature for mashing, which is between 65 and 67 degrees Centigrade. Getting the water much hotter than this is very difficult. We found it impossible to get the water to boil. 

troughs as mash tuns
The possibility that they were used in the making of ale or beer was first suggested by Declan Moore and Billy Quinn of Moore Archaeological and Environmental Services Ltd. I first met them at a Conference about beer and brewing in prehistory and antiquity, held in Barcelona, October 2004. I gave a paper about the importance of malt in the brewing process. Billy and Declan asked me whether it was possible to make beer in a hole in the ground. We agreed they should have a go.

The following year, they came to Orkney to meet Graham and to learn a bit more about how to make ale and beer from the grain. They tasted the wort and were surprised how sweet it is. They tried Graham's beer and liked it. Then they went back to Ireland to do their own research into hot rock mashing in a trough. It went extremely well, and led to their now famous video on You Tube. They wrote an article for Archaeology Ireland and there have been several more articles online since then. The details of their subsequent work are on their web page.

They gave a demonstration of the technique at the Sixth World Archaeology Conference in Dublin, 2008. I was lucky enough to be there and it was spectacular. The smoke, the steam, the hot stones and the aroma of the mash! All of these things added to the magic and drama of the demonstration. If an archaeologist is looking for an impressive show of ritual, power and transformation in prehistory, then a hot rock mash ticks all the boxes. 

One day in the summer of 2009, I got a phone call from Billy. He told me that a trough with grain in it had just been found in Wales. The well preserved trough, with wood lined water channels, was excavated by Dave Chapman of Ancient Arts who went on to do some mashing and brewing experiments of his own. He was successful, as reported in British Archaeology news.

We had to try this for ourselves. So far, we had been mashing small amounts of crushed malt in earthenware bowls. It was clear that the 'hot rocks in a trough' technique worked much better. Graham made a small wooden trough, about one third the size of the real ones, and we had some fun mashing with hot stones. It is best to use stones from the land. Rocks collected from the beach explode when being heated in the fire. This is very dangerous.

We had an opportunity to mash in the replica trough at Bressay, Shetland in the summer of 2011. The same trough that was used to experimentally wash fleeces. We cleaned it well and luted the corners with local clay, to prevent water leakage. This explains the grey colour of the water in the photo below. There was initially some concern that there might be a problem. It turned out to be the clearest, sparkliest ale we have ever made. Bentonite powder, a derivative of clay, is used today to clear wine and beer.

the strike: 50 kg of crushed malt is added to about 250 litres of hot water in the replica Cruester trough, Bressay, Shetland.
We used a garden fork to stir it about.

 

A successful mash. Adding a few hot stones kept the mash at an ideal temperature for the conversion of starch into sugar, which took about an hour. We put a piece of wood over the trough for heat retention. 

crushed malt & water transformed into 250 litres of wort in the trough, enough to make plenty of ale for a feast.

cheers! our clear and bright Bressay Ale.

After taking some of the wort from the trough using jugs, we added brewer's yeast and fermented it for several days. We only had one fermentation vessel, so we could not make use of more than 6 gallons of wort.

Next morning, when we went to empty and clean the trough, all the wort had drained away. Only the spent grain was left. Although we had clay luted it, the reconstructed trough is above the local water table. Meadowsweet flowers, about an ounce and a half, were added to the 6 gallons of wort when it had finished fermenting. Also, we had a ferry to catch and so our time was limited.

The result was a strong, clear ale. You can see all the pictures of our Bressay mashing and brewing adventure on my Facebook page. The ale kept really well.

We bottled it and sent some to the Past Horizons people to taste. It did take a while to open the parcel, but I think it was probably worth it.


neolithic burnt mounds, wooden tridents and fire cracked stones
There are excavations taking place in Northumberland, not far from Bamburgh Castle, organised by the Bamburgh Research Project. Several burnt mounds have been excavated and archaeomagnetromic dates that have so far been obtained indicate that these burnt mounds were in use during the Neolithic. Pottery finds support this interpretation. The dates obtained so far are 6,230 +/- 50 years BP at 95% confidence. There is a good summary of the excavations here.

Bishop Arnold of Soissons

In December last year, there was much discussion and argument on social media about some neolithic wooden tridents that had been found at a multi period site in Cumbria, which included several burnt mounds. What were these long handled wooden 'forks' used for? Fish prongs? Or maybe they were used for catching eels? Interpretations varied amongst archaeologists.

We think they would be a useful implement for stirring the crushed malt into the hot water - the strike. The crushed malt, also known as grist, clumps together when it is being added to the hot water. It is important to stir it about. It is also necessary to stir the mash when you add more heated stones. You don't want to have hot spots, you want to maintain an even temperature throughout the mash. The fork can also be used to move the hot stones about in the trough, if necessary.

In the Bressay trough, we used a garden fork. The handle was far too short and a long handled wooden trident would have been ideal.

Bishop Arnold of Soissons (who lived from 1040 to 1087) was the patron saint of brewers in Belgium. He is depicted with Bishop's mitre and a mash rake, which looks very much like those neolithic wooden rakes excavated in Cumbria.

Several neolithic buildings have been excavated at Kingsmead Quarry, Berkshire, England, by Wessex Archaeology. They have been interpreted as houses. This site is another very complex, multi period discovery, with finds ranging from the mesolithic, neolithic and Bronze Age through to post medieval structures.

One of the four neolithic rectangular timber buildings, or 'houses' at Horton caught our attention when we were looking at the images online. There seem to be some fire reddened rocks close by the trenches that reveal the outline of the building in the photo below. What are they? They look rather like modern bricks, but the stratigraphy indicates that they are contemporary with the building. Are these stones an indication of hot rock technology at neolithic Horton? If so, exactly what were they doing in and around this wooden building, over 5000 years ago?

the footprint of a neolithic rectangular timber building at Horton, Kingsmead Quarry, with a big pile of fire cracked stones.
Details of the excavation here.

 

We looked through the reports online but could not find a reference to them. Quite a mystery! Graham managed to enlarge the section of the image with the rocks in and here it is. In close up they look even more mysterious. We look forward to reading the full excavation report to see what the interpretation of these rocks might be.

a close up of those mysterious fire reddened stones.

We would love to hear your ideas about burnt mounds, troughs, mash tuns and the possibilities of hot stone technology. This technique, of heating water and the mash with hot stones, is so successful that it has been done from the Neolithic to Viking times. Some burnt mounds provide dates that indicate this.